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Senin, 10 Maret 2014

Anorganic Chemistry II Report



GOLD PANNING IN KAYUBOKO



I.              Background
On Inorganic Chemistry II lab, the experiment was not carried out in the laboratory. It is intended that the knowledge in terms of how to obtain the metal "gold" is not limited to knowledge in the laboratory.
 
The purpose of the present study took place in the village kayuboko. Kayuboko is a village located in the district of West Parigi Parigi District Moutong Central Sulawesi province. Distance to the center of the village Kayuboko Parigi district administration about 10 KM West, a distance of about 5 KM Capital District and the distance to the provincial capital of about 110 KM. Kayuboko village has 3 (three) and the Hamlet area of 12 square KM with boundaries - boundaries of the North: Village Baliara, Masigi Village, and the Village Mertasari; East: Pombolowo village, and the village of Olaya; South: Hot Springs Village; West: Lobu village continued to mount; Altitude Land of the Sea: Approximately 125 M; Rice Field: Approximately 142 Ha; Plantation: Approximately 1500 hectares; Yard: Approximately 148 Ha.
The reasons for the selection of villages kayuboko as the study site because it is pretty close and can be reached only by 2 hours by road.
 
In the village kayuboko, process mining is still largely traditional. One of them is by way of gain. In addition, those that are already using a machine called the 'dompeng'. However, when the weather was rather bad study causing flooding river water so that the mining process can only be done by panning.


II.           Literatur Review
Humans have known gold and treasured it since prehistoric times. Who discovered gold? We do not know, it was discovered before there were written records. We know there is a good chance the discoverer found it in a river bed. Currently we can trace our use of gold back to at least 6200 years ago. A variety of objects made of gold have been found in Bulgaria from 4500-4000 BC.
Gold artifacts dated to 5000 years ago have been found in Egyptian tombs; gold was already being beaten into sheets, foil and wire in Egypt at this time.  The Egyptian word for gold was ‘nub’ and is related to Nubia, the land south of Egypt where much of Egypt’s gold was obtained.
Gold in the native state (i.e. found naturally) is usually mixed with other metals, such as silver. Its purity can be increased by depletion guilding or refining – a significant step forward in technology.
Gold of 98% purity has been found in Nahal Qunah in the ancient kingdom of Israel, dating from about 6000 years ago. Analyses of gold from ancient Egypt indicates refining began there about 2500 years ago.
The legendary wealth of King Croesus of Lydia (now in modern Turkey) came from refining gold found in several local rivers. Gold became the basis of money in many ancient civilizations, and even today most countries maintain large reserves of gold for financial credibility. Most modern currencies, however, are not tied to gold as they were in the days of the Gold Standard, described by economist John Maynard Keynes as “a barbarous relic.”
In ancient times people viewed gold as the perfect substance. Alchemists began a relentless but fruitless pursuit spanning many centuries, trying to discover how to transform other metals into gold.
Although alchemy failed in its goal, the experimental techniques alchemists developed were important to the early chemists. Alchemists believed gold was made of a mixture of perfectly purified mercury and sulfur, mixed in the perfect proportions.
Constant failure to produce gold simply meant substances were not yet pure enough, or the perfect proportions had not yet been found. Alchemist’s concepts of mercury and sulfur were different from ours; while they did include the substances we call mercury and sulfur, they also encompassed other metals and substances.
The word ‘gold’ is an Anglo-Saxon word, similar to the Anglo-Saxon word for yellow, ‘geolo.’ It is believed to have come from the Sanskrit ‘jval’ meaning ‘to shine.’ The chemical symbol Au comes from ‘aurum’ the Latin word for gold. (Aurora was goddess of dawn or the morning glow.)
*             Gold is a metallic element
Elements are the building blocks of our planet and gold is one of 94 naturally occurring elements. It is a metallic material with a distinct yellow colour and metallic lustre. Its Atomic Number is 79, its Atomic Mass is 196.967 and its symbol is Au.
Gold is not an abundant element. It is estimated gold atoms comprise only 0.3 parts per billion [ppb] of the Earth’s crust. This translates to 3.1 ppb by weight due to its density. However, sometimes geological processes concentrate gold into ore deposits where it may be present in amounts above 5 parts per million [ppm] by weight and sometimes as solid nuggets.
*             Properties of gold
Gold is highly valued for many reasons but its physical properties are essential to the functioning of modern society. Gold is very soft [2.5 - 3.0 on the mohs hardness scale] and is the most malleable and ductile of metals. This means it can be beaten into very thin sheets and drawn out into very thin wires. Gold does not readily form compounds and does not oxidise or tarnish. Only a mixture of hydrochloric acid and nitric acid [called ‘aqua regia’], some cyanide solutions and mercury will dissolve gold under surface temperatures and pressures. 
 gold
All metals conduct heat and electricity; gold is no exception. In fact it is a better conductor than most metals. Silver is a better electrical conductor but gold is the metal of choice in mission-critical situations due to its ability to also resist corrosion.
The melting point of gold is 1064oC and it boils to a vapour at 2856oC. Gold is a very dense material. It has a specific gravity or density of 19.3. This means 1cm3 weighs 19.3 grams while 1cm3 of water only weighs 1 gram.
*             Measuring gold
Gold has a long history of use in society so it is no surprise that measurements of gold involve old and somewhat obscure units. Gold is always traded in Troy ounces. Take note: a Troy ounce is not the same as other ounces.
1 Troy Ounce = 31.1 grams
Because gold is so soft it is often alloyed with other metals in order to improve its durability. Commonly it is mixed with copper, platinum or nickel. Gold alloys are rated using the 24 point carat system. 24 carat gold is pure (100% Au w/w), 18-carat gold is 75% gold by weight and 12-carat gold is 50% gold by weight. The carat system is also applied to Platinum.
Just be careful though. This system refers to gold content by weight. Sometimes people assume a given purity to mean the amount by volume. With gold being such a dense material 50% gold by weight does not mean 50% gold by volume.
Bullion dealers sometimes quote gold purity using ‘fineness’. 4 nines fineness or 9999 fineness is simply another way of saying 99.99% gold! 4 nines gold is effectively 24 carat gold.
III.             Method
a.       Tools
As for the tools in the panning is as follows:
·         Coconut shell
·         Pan
·         Bucket

b.      Materials
The material used in the panning process is sands from the
bottom of river.

c.       Working Procedures
1)      Prepare equipment and materials to be used.
2)      Find a stretch of river that is at least 6 inches deep and where the water runs fast enough.
3)      Entering into the pan as river gravel ¾ of volume and pan position remains in the water pan.
4)      Issued pebbles large enough and the dirt from the pan.
5)      Having just left paisir-sand small size, then shaken pan left and right.
6)      Sweep of the sand surface of the pan using the hand shot up.
7)      Repeat steps 5 and 6 until the black sand looks.
8)      Having seen black sand, shaken pan with a circular motion with the pan tilt on one side.
9)      Repeat steps 9 through visible gold.
10)  Accommodate gold obtained in the bucket provided.


IV.        Discussion
Gold is an excellent conductor of heat and electricity. It is a soft, yellow, metal with a beautiful lustrous sheen. It is the most malleable and ductile of all the elements and a single gram can be beaten into a sheet one square meter sheet of gold leaf.
Gold is widely used in jewelry and coinage. It is also used in dental work as crowns, as gold plating for decoration and as gold thread in embroidery work. The gold content in alloys is usually measured in carats (k), with pure gold defined as 24k.
Panning for gold is a simple process, but one that takes a little practice to master. It relies on the principle of specific gravity – the density of a substance relative to the density of water. The higher the specific gravity of a substance, the greater its propensity to sink to the bottom of a container of water. As gold has a very high specific gravity, this principle can be used to separate it from the material within which it is found.
The purpose of this experiment is to determine how the process of gold mining in the village kayuboko. Gold mining process is still traditional village that is the way panning.
The first step that needs to be done is to prepare a tool that will be used. The tools used in the form of coconut shell that serves to take sand from the river, which serves as a panning tray and scoop that serves to menapung gold have been obtained.
The second, choose a spot to do your panning. It is best to pick a location where the water is at least six inches deep and preferably flowing just enough to sweep away any silty water that may be washed from your pan. This way, you can see what you are doing better. You do not want the water moving so swiftly that it will upset your panning actions. A mild current will do, if available. It is always best to find a spot where there’s a rock or log or stream-bank or something that you can sit down upon while panning. You can pan effectively while squatting, kneeling or bending over, but it does get tiresome. If planning to process more than just one or two pans, sitting down will make the activity much more pleasant.
The third pan to enter river pebbles into the pan as much as ¾ of volume and pan position remains in the water. It aims to to wash away the mud, clay, gravel, sand etc. but retain whatever gold is mixed with this material. The pan should be underwater while doing this. Mud and silt will float up and out. Do not concern yourself about losing any gold when this happens. Remember: gold is heavy and will sink deeper in your pan while these lighter materials are floating out and away.
The fourth, is issued pebbles large enough to facilitate the process of panning.
The fifth, after the only remaining sand paisir-small size, then shaken pan left and right to pan position remains under the surface of the water. It is intended that the material has a density of large (gold) will be getting down and remain behind in the pan while having a small density will be lifted to the surface. Then sweep sand the surface with a hand raised slowly so gold is not carried.
Then repeat the steps above until a few times until the only remaining black sand.
Sixth, after the black sand looks, shaken pan with a circular motion with the pan tilt on one side slowly. It is intended that water will sweep the black sand bit by bit. This step is repeated multiple times and must be done very carefully so as not participate swept gold.
Finally, after the gold has been clean of impurities from then collected in buckets.
Based on interviews with the miners in the village mrs. Gamar (58 years old) and mrs. Nurmin (40 years) said that the gold they earn will be collected up to 2 weeks and then sold to collectors. In addition, the miners say that they do not use chemicals in the treatment process because the results obtained only gold collected and then sold.

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